Growth and characterization of delafossite-type Pd(Co1-xMnx)O2 (x=0.04, 0.11) single crystals

被引：3

作者：

Tanaka, M

Hasegawa, M ^{[1
]}

Takei, H

机构：

[1] Univ Tokyo, Inst Solid State Phys, Minato Ku, Tokyo 1068666, Japan

[2] Osaka Univ, Grad Sch Sci, Toyonaka, Osaka 5600043, Japan

来源：

JOURNAL OF CRYSTAL GROWTH | 1999年 / 203卷 / 03期

关键词：

Pd(Co; Mn)O-2; metathetical reaction; delafossite type structure; crystal morphology; magnetic susceptibility;

D O I：

10.1016/S0022-0248(99)00112-8

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Solid solution crystals of Pd(Co1-xMnx)O-2 (x = 0.04, 0.11) of high quality have been successfully grown using a metathetical reaction. The maximum crystal sizes of Pd(Co0.96Mn0.04)O-2 and Pd(Co0.89Mn0.11)O-2 are about 0.6(a) x 0.6(a) x 0.9(c) mm(3) and 0.2(a) x 0.2(a) x 0.6(c) mm(3), respectively. The crystals show silver metallic luster and an well-habited. The crystals have a polyhedral-barrel shape which is clearly different from the hexagonal plate shape of purl PdCoO2 crystals. In the crystals of Pd(Co0.89Mn0.11)O-2, a broad cusp at about 18 K is observed in the temperature dependence of magnetization in a low magnetic field. (C) 1999 Published by Elsevier Science B.V. All rights reserved.

引用

页码：400 / 404

页数：5

共 9 条

[1]

PREWITT CT, 1971, INORG CHEM, V10, P719

[2]

ROGERS DB, 1971, INORG CHEM, V10, P723

[3] EFFECTIVE IONIC RADII IN OXIDES AND FLUORIDES [J].