Intrazeolite photooxidations of electron-poor alkenes

被引：26

作者：

Clennan, EL ^{[1
]}

Sram, JP ^{[1
]}

Pace, A ^{[1
]}

Vincer, K ^{[1
]}

White, S ^{[1
]}

机构：

[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 11期

关键词：

D O I：

10.1021/jo025657c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The inability of the intrazeolite environment to influence the regiochemistry of addition of singlet oxygen to electron-poor olefins is reported. This divergent behavior with respect to electron-rich alkenes is rationalized with a multicomplexation model that emphasizes the importance of intrazeolite substrate-cation binding.

引用

收藏

页码：3975 / 3978

页数：4

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