A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn(4,4′-bipyridine)2(H2O)4]2+ cations and rich solvate 4,4′-bipyridine molecules through hydrogen-bonding and π-π interactions

被引：161

作者：

Tong, ML

Lee, HK ^{[1
]}

Chen, XM

Huang, RB

Mak, TCW

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 21期

关键词：

D O I：

10.1039/a907111c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solid compound formulated as [Mn(4,4'-bpy)(2)(H2O)(4)][ClO4](2).(4,4'-bpy)(4) (bpy=bipyridine) has been shown by single-crystal structural analysis to be a three-dimensional network with triangular channels, which are constructed by mononuclear [Mn(4,4'-bpy)(2)(H2O)(4)](2+) cations and 4,4'-bpy molecules through extensive hydrogen-bonds and pi-pi interactions.

引用

页码：3657 / 3659

页数：3

共 36 条

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