A simple and "green" method for the synthesis of Au, Ag, and Au-Ag alloy nanoparticles

被引:511
作者
Raveendran, P
Fu, J
Wallen, SL
机构
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
[2] Univ N Carolina, NSF STC Environm Responsible Solvents & Proc, Chapel Hill, NC 27599 USA
[3] Natl Inst Adv Ind Sci & Technol, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
D O I
10.1039/b512540e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Integration of "green chemistry" principles into nanotechnology is one of the key issues in nanoscience research today. In this work, we report an environmentally benign method for the preparation of Au, Ag, and Au-Ag nanoparticles in water, using glucose as the reducing agent and starch as the protecting agent. The alloy nanoparticles prepared in this way appears to be homogeneous and their sizes are well within the quantum size domain (<10 nm), where they are more amenable to size-dependent changes in electronic properties.
引用
收藏
页码:34 / 38
页数:5
相关论文
共 37 条
[31]   OBSERVATION OF PLASMON FREQUENCY IN THE OPTICAL-SPECTRUM OF AU18AG20 CLUSTER - THE BEGINNING OF THE COLLECTIVE PHENOMENON CHARACTERISTIC OF THE BULK [J].
TEO, BK ;
KEATING, K ;
KAO, YH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (11) :3494-3495
[32]   POLYMER-PROTECTED PALLADIUM-PLATINUM BIMETALLIC CLUSTERS - PREPARATION, CATALYTIC PROPERTIES AND STRUCTURAL CONSIDERATIONS [J].
TOSHIMA, N ;
YONEZAWA, T ;
KUSHIHASHI, K .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (14) :2537-2543
[33]  
ULLMAN A, 1996, CHEM REV, V96, P1533
[34]   Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties [J].
Valden, M ;
Lai, X ;
Goodman, DW .
SCIENCE, 1998, 281 (5383) :1647-1650
[35]  
Wang RY, 2001, ANGEW CHEM INT EDIT, V40, P549, DOI 10.1002/1521-3773(20010202)40:3<549::AID-ANIE549>3.0.CO
[36]  
2-P
[37]   Preparation of Cu nanoclusters within dendrimer templates [J].
Zhao, MQ ;
Sun, L ;
Crooks, RM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (19) :4877-4878