Electronic absorption spectra of carbon chain anions C-2n+1(-) (n=2-5) in neon matrices

被引：32

作者：

Forney, D ^{[1
]}

Grutter, M ^{[1
]}

Freivogel, P ^{[1
]}

Maier, JP ^{[1
]}

机构：

[1] UNIV BASEL,INST PHYS CHEM,CH-4056 BASEL,SWITZERLAND

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 29期

关键词：

D O I：

10.1021/jp970954k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Absorption spectra showing transitions to several excited electronic states of C-2n+1(-) (n = 2-5) chains were observed. The spectra were recorded after codeposition of mass-selected anions with neon to form a matrix at 5 K. The assignment follows from mass-selection, the monotonic dependence of the wavelength of the electronic origin band on the number of carbon atoms, photobleaching changes, and spectroscopic considerations. The absorption band systems can be attributed to (2) Pi <-- X (2) Pi. transitions. For C-5(-) two transitions are observed, for C-7(-) three, and for C-9(-) and C-11(-) four.

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页码：5292 / 5295

页数：4

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