Light harvesting and efficient energy transfer in a boron-dipyrrin (BODIPY) functionalized perylenediimide derivative

被引:178
作者
Yilmaz, M. Deniz [1 ]
Bozdemir, O. Altan
Akkaya, Engin U.
机构
[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
[2] Akdeniz Univ, Dept Chem, TR-07058 Antalya, Turkey
关键词
D O I
10.1021/ol061110z
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Click chemistry has been successfully applied in the synthesis of a bay region tetraboron-dipyrrin (BODIPY) appended perylenediimide (PDI). This light-harvesting molecule presents a large cross section for the absorption of light in the visible region. Excitation energy is efficiently channeled to the perylenediimide core. This novel antenna system is the first demonstration of the efficiency of energy transfer in a BODIPY-PDI bichromophoric system and appears to be highly promising for the design and synthesis of similar dendritic structures.
引用
收藏
页码:2871 / 2873
页数:3
相关论文
共 26 条
[1]   Light-harvesting dendrimers [J].
Adronov, A ;
Fréchet, JMJ .
CHEMICAL COMMUNICATIONS, 2000, (18) :1701-1710
[2]   Light-harvesting dendrimers [J].
Balzani, V ;
Ceroni, P ;
Maestri, M ;
Vicinelli, V .
CURRENT OPINION IN CHEMICAL BIOLOGY, 2003, 7 (06) :657-665
[3]  
BALZANI V, 2002, MOL DEVICES MACHINES
[4]   Multichromophoric cyclodextrins. 8. Dynamics of homo- and heterotransfer of excitation energy in inclusion complexes with fluorescent dyes [J].
Berberan-Santos, MN ;
Choppinet, P ;
Fedorov, A ;
Jullien, L ;
Valeur, B .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (48) :11876-11886
[5]   Fluorescence resonance energy transfer in a novel two-photon absorbing system [J].
Brousmiche, DW ;
Serin, JM ;
Fréchet, JMJ ;
He, GS ;
Lin, TC ;
Chung, SJ ;
Prasad, PN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (06) :1448-1449
[6]   Functionally layered dendrimers:: A new building block and its application to the synthesis of multichromophoric light-harvesting systems [J].
Dichtel, WR ;
Hecht, S ;
Fréchet, JMJ .
ORGANIC LETTERS, 2005, 7 (20) :4451-4454
[7]  
Herrmann A, 2001, CHEM-EUR J, V7, P4844, DOI 10.1002/1521-3765(20011119)7:22<4844::AID-CHEM4844>3.0.CO
[8]  
2-1
[9]   Energy transfer within perylene-terrylene dendrimers evidenced by polychromatic transient absorption measurements [J].
Jordens, Sven ;
De Belder, Gino ;
Lor, Marc ;
Schweitzer, Gerd ;
Van der Auweraer, Mark ;
Weil, Tanja ;
Reuther, Erik ;
Muellen, Klaus ;
De Schryver, Frans C. .
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2003, 2 (03) :177-186
[10]   Photoinduced electron and energy transfer processes in a bichromophoric pyrene-perylene bisimide system [J].
Kaletas, BK ;
Dobrawa, R ;
Sautter, A ;
Würthner, F ;
Zimine, M ;
De Cola, L ;
Williams, RM .
JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (11) :1900-1909