Asymmetric [2+2] photocycloaddition of cycloalkenone-cyclodextrin complexes to ethylene

被引：14

作者：

Furutani, A

Katayama, K

Uesima, Y

Ogura, M

Tobe, Y

Kurosawa, H

Tsutsumi, K

Morimoto, T

Kakiuchi, K ^{[1
]}

机构：

[1] NAIST, Grad Sch Mat Sci, Nara 6300192, Japan

[2] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka, Japan

[3] Osaka Univ, Grad Sch Engn Sci, Toyonaka, Osaka 560, Japan

来源：

CHIRALITY | 2006年 / 18卷 / 03期

关键词：

cyclodextrin; photocycloaddition; cycloalkenone; enantioselectivity; ethylene;

D O I：

10.1002/chir.20232

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The enantioselective [2+2] photocycloaddition of cycloalkenone-cyclodextrin complexes to ethylene was examined. Pbotoreaction of alpha-, beta-, and gamma-cyclodextrin complexes of various cyclohexenonecarboxylates and cyclopentenonecarboxylates in the presence of ethylene in the solid state or in aqueous suspension gave corresponding photocycloadducts with chiral induction. (c) 2006 Wiley-Liss, Inc.

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页码：217 / 221

页数：5

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