Intercepting palladacycles derived by C-H insertion. A mechanism-driven entry to heterocyclic tetraphenylenes

被引：94

作者：

Masselot, D

Charmant, JPH

Gallagher, T ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Bristol, Struct Chem Lab, Bristol BS8 1TS, Avon, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 03期

关键词：

D O I：

10.1021/ja056964d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mechanistic support for the intermediacy of a palladacycle, which has been implicated in the crossover Heck reaction, has been obtained by intercepting this species using biphenylene. This leads to the formation of heterocyclic tetraphenylene derivatives. Three examples of this process are reported, and in two cases, the product structures have been confirmed by X-ray crystallographic analysis. Copyright © 2006 American Chemical Society.

引用

页码：694 / 695

页数：2

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