Novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryis

被引：148

作者：

Campo, MA ^{[1
]}

Larock, RC ^{[1
]}

机构：

[1] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 48期

关键词：

D O I：

10.1021/ja027548l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryls has been observed under modified Heck reaction conditions. This migration process can be switched "on" or "off" by simply choosing the appropriate reaction conditions. Copyright © 2002 American Chemical Society.

引用

页码：14326 / 14327

页数：2

共 12 条

[1] RECENT DEVELOPMENTS AND NEW PERSPECTIVES IN THE HECK REACTION
CABRI, W
CANDIANI, I
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) : 2 - 7
[2] FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB
DE MEIJERE, A
MEYER, FE
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) : 2379 - 2411
[3] Heck reactions under microwave irradiation in solvent-free conditions
DiazOrtiz, A
Prieto, P
Vazquez, E
[J]. SYNLETT, 1997, (03) : 269 - &
[4] The intramolecular Heck reaction
Gibson, SE
Middleton, RJ
[J]. CONTEMPORARY ORGANIC SYNTHESIS, 1996, 3 (06): : 447 - 471
[5] HECK RF, 1982, ORG REACTIONS, V27, P345
[6] PALLADIUM-CATALYZED VINYLATION OF ORGANIC HALIDES UNDER SOLID LIQUID-PHASE TRANSFER CONDITIONS
JEFFERY, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (19) : 1287 - 1289
[7] C-H activation and palladium migration within biaryls under Heck reaction conditions
Karig, G
Moon, MT
Thasana, N
Gallagher, T
[J]. ORGANIC LETTERS, 2002, 4 (18) : 3115 - 3118
[8] Synthesis of 9-alkylidene-9H-fluorenes by a novel, palladium-catalyzed cascade reaction of aryl halides and 1-aryl-1-alkynes
Larock, RC
Tian, QP
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (22) : 7372 - 7379
[9] Synthesis of polycyclic aromatic hydrocarbons by the Pd-catalyzed annulation of alkynes
Larock, RC
Doty, MJ
Tian, QP
Zenner, JM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (22) : 7536 - 7537
[10] APPLICATION OF INTRAMOLECULAR HECK REACTIONS FOR FORMING CONGESTED QUATERNARY CARBON CENTERS IN COMPLEX MOLECULE TOTAL SYNTHESIS
OVERMAN, LE
[J]. PURE AND APPLIED CHEMISTRY, 1994, 66 (07) : 1423 - 1430

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