Nanometer-sized titania hosted inside MOF-5

被引:84
作者
Mueller, Maike [1 ]
Zhang, Xiaoning [1 ]
Wang, Yuemin [1 ]
Fischer, Roland A. [1 ]
机构
[1] Ruhr Univ Bochum, D-44780 Bochum, Germany
关键词
THERMAL-STABILITY; TIO2; NANOPARTICLES; ANATASE; CRYSTALLIZATION; PRECURSORS; FRAMEWORKS; SILICA;
D O I
10.1039/b814241f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanoscale titania particles were synthesized inside the porous coordination polymer [Zn4O(bdc)(3)] (bdc = 1,4-benzene-dicarboxylate, MOF-5) by adsorption of titanium isopropoxide from the gas-phase and subsequent dry oxidation and annealing.
引用
收藏
页码:119 / 121
页数:3
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共 26 条
[1]   Synthesis of morphology-controlled titania nanocrystals and application for dye-sensitized solar cell's [J].
Adachi, Motonari ;
Jiu, Jinting ;
Isoda, Seiji .
CURRENT NANOSCIENCE, 2007, 3 (04) :285-295
[2]   Enhancement of the photocatalytic activity of TiO2 through spatial structuring and particle size control:: from subnanometric to submillimetric length scale [J].
Aprile, Carmela ;
Corma, Avelino ;
Garcia, Hermenegildo .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (06) :769-783
[3]   Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour [J].
Bordiga, S ;
Lamberti, C ;
Ricchiardi, G ;
Regli, L ;
Bonino, F ;
Damin, A ;
Lillerud, KP ;
Bjorgen, M ;
Zecchina, A .
CHEMICAL COMMUNICATIONS, 2004, (20) :2300-2301
[4]   Unusual crystallization behaviors of anatase nanocrystallites from a molecularly thin titania nanosheet and its stacked forms: Increase in nucleation temperature and oriented growth [J].
Fukuda, Katsutoshi ;
Ebina, Yasuo ;
Shibata, Tatsuo ;
Aizawa, Takashi ;
Nakai, Izumi ;
Sasaki, Takayoshi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (01) :202-209
[5]   Mesoporous silica supports for improved thermal stability in supported Au catalysts [J].
Gabaldon, John P. ;
Bore, Mangesh ;
Datye, Abhya K. .
TOPICS IN CATALYSIS, 2007, 44 (1-2) :253-262
[6]   Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems [J].
Gaya, Umar Ibrahim ;
Abdullah, Abdul Halim .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2008, 9 (01) :1-12
[7]   The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities [J].
Hafizovic, Jasmina ;
Bjorgen, Morten ;
Olsbye, Unni ;
Dietzel, Pascal D. C. ;
Bordiga, Silvia ;
Prestipino, Carmelo ;
Lamberti, Carlo ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (12) :3612-3620
[8]   Metal@MOF:: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition [J].
Hermes, S ;
Schröter, MK ;
Schmid, R ;
Khodeir, L ;
Muhler, M ;
Tissler, A ;
Fischer, RW ;
Fischer, RA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (38) :6237-6241
[9]   Loading of porous metal-organic open frameworks with organometallic CVD precursors:: inclusion compounds of the type [LnM]a@MOF-5 [J].
Hermes, Stephan ;
Schroeder, Felicitas ;
Amirjalayer, Saeed ;
Schmid, Rochus ;
Fischer, Roland A. .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (25) :2464-2472
[10]   Selective photo-deposition of Cu onto the surface of monodisperse oleic acid capped TiO2 nanorods probed by FT-IR CO-adsorption studies [J].
Hikov, T ;
Schroeter, MK ;
Khodeir, L ;
Chemseddine, A ;
Muhler, M ;
Fischer, RA .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (13) :1550-1555