Interaction of metal ions with D-glucobenzothiazoline: isolation and characterization of the resultant products

被引：8

作者：

Das, TM

Rao, CP ^{[1
]}

Kolehmainen, E

Kadam, RM

Sastry, MD

机构：

[1] Indian Inst Technol, Dept Chem, Bioinorgan Lab, Mumbai 400076, India

[2] Univ Jyvaskyla, Dept Chem, SF-40351 Jyvaskyla, Finland

[3] Bhabha Atom Res Ctr, Div Radiochem, Mumbai 400085, India

来源：

CARBOHYDRATE RESEARCH | 2002年 / 337卷 / 04期

关键词：

benzothiazoline derivatives; anomeric mixture; beta anomer; levorotatory; bonding and structural group parameters; inversion of conformation; simulated spectrum;

D O I：

10.1016/S0008-6215(01)00317-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Six different metal-ion complexes of D-glucobenzothiazoline were synthesized and characterized by analytical and spectral techniques. Formation of different types of species (ML and ML2) were observed with Cu2+, Ag+, Cd2+, Hg2+, and Zn2+ ions. Existence of an anomeric mixture in the case of the Cu2+ complex is identified from the EPR spectra, and the results were further supported by the simulated spectra. The structures were proposed based on different studies. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：289 / 296

页数：8

共 19 条

[1] SYNTHESIS AND CHARACTERIZATION OF SOME DIBASIC TRIDENTATE SCHIFF-BASE LIGANDS [J].