Stereoselective alternating copolymerization of carbon monoxide with alkenes

被引：113

作者：

Nozaki, K ^{[1
]}

Hiyama, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 576卷 / 1-2期

关键词：

palladium; stereoselective; asymmetric; alternating copolymerization; carbon monoxide; alkene;

D O I：

10.1016/S0022-328X(98)01062-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stereoselective alternating copolymerization of carbon monoxide with various alkenes is reviewed. Using Pd(II) complexes of chiral ligands, completely alternating, isotactic, and enantioselective copolymerizations have been achieved from aliphatic 1-alkenes and from vinylarenes. Alternating copolymerization of carbon monoxide with other olefins are also described, such as functionalized ones, dienes, and allenes. Polymer conformation is mentioned briefly both in solid phase and in solution. (C) 1999 Elsevier Science S.A. All rights reserved.

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收藏

页码：248 / 253

页数：6

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