Enantioselective alternating terpolymerization of styrene and ethene with carbon monoxide - Preliminary communication

被引：38

作者：

Aeby, A ^{[1
]}

Consiglio, G ^{[1
]}

机构：

[1] ETH Zentrum, Tech Chem Lab, CH-8092 Zurich, Switzerland

来源：

HELVETICA CHIMICA ACTA | 1998年 / 81卷 / 01期

关键词：

D O I：

10.1002/hlca.19980810104

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In spite of the higher reactivity of styrene with respect to ethene for the alternating copolymerization with carbon monoxide, catalyzed by chiral (dihydrooxazole)(phosphino)palladium complexes, ethene is preferentially (and randomly) enchained in terpolymerization experiments; enantioface selection for styrene is comparably high in both copolymerization and terpolymerization processes.

引用

页码：35 / 39

页数：5

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