A caveat concerning anionic oxy-cope rearrangements within bicyclo[2.2.2]octenyl frameworks

被引：22

作者：

Banwell, MG ^{[1
]}

Dupuche, JR ^{[1
]}

Gable, RW ^{[1
]}

机构：

[1] UNIV MELBOURNE,DEPT CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1996年 / 49卷 / 05期

关键词：

D O I：

10.1071/CH9960639

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compounds (10), (15) and (16) all react with potassium hydride at 0 degrees C to give, via retro-Diels-Alder reaction, 1-methylnaphthalene (12) in 60-67% yield. No evidence could be obtained for the formation of a product derived from the anionic oxy-Cope rearrangement of substrate (16).

引用

页码：639 / 645

页数：7

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