Challenges and opportunities for mixed-matrix membranes for gas separation

被引:589
作者
Dong, Guangxi [1 ,2 ]
Li, Hongyu [1 ,2 ]
Chen, Vicki [1 ]
机构
[1] Univ New S Wales, Sch Chem Engn, UNESCO Ctr Membrane Sci & Technol, Sydney, NSW 2052, Australia
[2] Univ New S Wales, Sch Chem Engn, Cooperat Res Ctr Greenhouse Gas Technol CO2CRC, Sydney, NSW 2052, Australia
基金
澳大利亚研究理事会;
关键词
METAL-ORGANIC FRAMEWORKS; POLYMER-CHAIN RIGIDIFICATION; POROUS COORDINATION POLYMER; NANOPOROUS CARBON MEMBRANES; MOLECULAR-SIEVE; NANOCOMPOSITE MEMBRANES; PERMEATION PROPERTIES; THERMAL-CONDUCTIVITY; MESOPOROUS SILICA; GLASSY-POLYMERS;
D O I
10.1039/c3ta00927k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mixed-Matrix Membranes (MMMs) combining the benefits of both polymeric and inorganic materials have become a focus for the next-generation gas separation membranes. In this review, major challenges surrounding MMMs and the strategies to tackle these challenges are given in detail. The selection criteria of polymeric and inorganic materials are discussed in terms of their physical and chemical compatibility as well as large scale fabrication issues. Major models for separation performance prediction of MMMs are reviewed in terms of their interrelations and limitations. A discussion is provided regarding the future direction of MMMs.
引用
收藏
页码:4610 / 4630
页数:21
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