Direct Patterning of Oriented Metal-Organic Framework Crystals via Control over Crystallization Kinetics in Clear Precursor Solutions

被引：217

作者：

Ameloot, Rob ^{[1
]}

Gobechiya, Elena ^{[1
]}

Uji-i, Hiroshi ^{[2
]}

Martens, Johan A. ^{[1
]}

Hofkens, Johan ^{[2
]}

Alaerts, Luc ^{[1
]}

Sels, Bert F. ^{[1
]}

De Vos, Dirk E. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Dept Microbial & Mol Syst, B-3001 Louvain, Belgium

[2] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 24期

关键词：

FIELD-EFFECT TRANSISTORS; COPPER(II) ION; GROWTH; WATER; SOLVATION; DIMETHYLSULFOXIDE; CU-3(BTC)(2); MONOLAYERS; COATINGS; ROUTE;

D O I：

10.1002/adma.200903867

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Processing metal organic frameworks with spatial and temporal control over crystal formation will increase the applicability of these highly porous materials. By exploiting solvent effects, stable synthesis solutions can be obtained, which can be used in combination with soft lithographic techniques to deposit oriented crystals in patterns by in situ crystallization (see figure).

引用

页码：2685 / +

页数：5

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