Aromatic C-F activation at Ni in the presence of a carbon-chlorine bond: the nickel mediated synthesis of new pyrimidines

被引：67

作者：

Sladek, MI ^{[1
]}

Braun, T ^{[1
]}

Neumann, B ^{[1
]}

Stammler, HG ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 03期

关键词：

D O I：

10.1039/b110128e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [Ni(COD)(2)]/PCy3 with 5-chloro-2,4,6-trifluoropyrimidine affords the C-F activation product trans-[NiF(4-C4N2ClF2)(PCy3)(2)](2), which reacts with iodine to form 5-chloro-2,6-difluoro-4-iodo-pyrimidine 5.

引用

页码：297 / 299

页数：3

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