A new efficient deprotection of azines, hydrazones and oximes. An excellent route for exchanging oxygen isotopes in carbonyls

被引：19

作者：

Carmeli, M ^{[1
]}

Rozen, S ^{[1
]}

机构：

[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 05期

基金：

以色列科学基金会;

关键词：

D O I：

10.1016/j.tetlet.2005.11.090

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbonyls, protected as azines or other C=N derivatives can be deprotected by (HOFCH3CN)-C-. in seconds to the corresponding ketone or aldehyde in very good yields. This reaction also offers a very efficient route for replacing the oxygen atom of most carbonyls with any other oxygen isotope, for example, [18]O. (c) 2005 Elsevier Ltd. All rights reserved.

引用

收藏

页码：763 / 766

页数：4

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