Structural study of three isomers of Tm@C82 by 13C NMR spectroscopy

被引：55

作者：

Kodama, T ^{[1
]}

Ozawa, N ^{[1
]}

Miyake, Y ^{[1
]}

Sakaguchi, K ^{[1
]}

Nishikawa, H ^{[1
]}

Ikemoto, I ^{[1
]}

Kikuchi, K ^{[1
]}

Achiba, Y ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Chem, Hachioji, Tokyo 1920397, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 07期

关键词：

D O I：

10.1021/ja005839t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-13 NMR spectra were measured for three isomers of Tm@C-82, which is one of the divalent metallofullerenes. The molecular symmetries were determined for each isomer: isomer I has Q symmetry, isomer II has C-2 symmetry, and isomer III has C-2v symmetry. Moreover the cage structure of Tm@C-82(III) was found to be C-82(9). As a result, it was revealed that Tm@C-82(III) has a cage identical to that of La@C-82, which is one of the trivalent metallofullerenes.

引用

页码：1452 / 1455

页数：4

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