Novel expanded porphyrin sensitized solar cells using boryl oxasmaragdyrin as the sensitizer

被引：43

作者：

Mane, Sandeep B. ^{[1
,2
]}

Hu, Jyun-Yu ^{[3
,4
]}

Chang, Yu-Cheng ^{[3
,4
]}

Luo, Liyang ^{[5
]}

Diau, Eric Wei-Guang ^{[3
,4
]}

Hung, Chen-Hsiung ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan

[3] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 300, Taiwan

[4] Natl Chiao Tung Univ, Inst Mol Sci, Hsinchu 300, Taiwan

[5] Chung Yuan Christian Univ, Dept Chem, Chungli 32023, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 61期

关键词：

SMARAGDYRINS; EFFICIENCY; ANION;

D O I：

10.1039/c3cc42769b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxasmaragdyrin boron complexes were prepared and applied in DSSCs. The HOMO-LUMO energy gap analyses and theoretical calculations revealed that these expanded porphyrins are ideal sensitizers for DSSCs. A device containing oxasmaragdyrin-BF2 as the sensitizer achieves an energy conversion efficiency of 5.7%.

引用

页码：6882 / 6884

页数：3

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