Alternated Stacks of Nonpolar Oligo(p-phenyleneethynylene)-BODIPY Systems

被引:45
作者
Florian, Alexander [1 ,2 ]
Mayoral, Maria Jose [1 ,2 ]
Stepanenko, Vladimir [1 ,2 ]
Fernandez, Gustavo [1 ,2 ]
机构
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
[2] Univ Wurzburg, Ctr Nanosyst Chem, D-97074 Wurzburg, Germany
关键词
conjugated systems; BODIPY dyes; pi interactions; self-assembly; supramolecular chemistry; DIPYRROMETHENEBORON DIFLUORIDE BODIPY; SOLAR-CELLS; ENERGY-TRANSFER; SPECTROSCOPIC PROPERTIES; PHOTODYNAMIC THERAPY; COLUMNAR MESOPHASES; FLUORESCENT-PROBE; CHARGED BODIPY; LASER-DYES; DERIVATIVES;
D O I
10.1002/chem.201203279
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular chemistry: The self-assembly of an oligo(p- phenyleneethynylene)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (OPE-BODIPY) system into alternated 1D π stacks in solution exhibited liquid-crystalline properties at room temperature. This system represents a new approach towards a controlled dye organization exclusively driven by π-π interactions (see figure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:14957 / 14961
页数:5
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