From vesicles to helical nanotubes:: A sergeant-and-soldiers effect in the self-assembly of oligo(p-phenyleneethynylene)s

被引：189

作者：

Ajayaghosh, Ayyappanpillai ^{[1
]}

Varghese, Reji ^{[1
]}

Mahesh, Sankarapillai ^{[1
]}

Praveen, Vakayil K. ^{[1
]}

机构：

[1] CSIR, Reg Res Lab, Chem Sci & Technol Div, Photosci & Photon Grp, Trivandrum 695019, Kerala, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 46期

关键词：

circular dichroism; helical structures; nanotubes; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200603238

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coassembly of short molecular wires OPE1 with chiral analogues OPE2, both of which are CD silent, exhibited a sergeant-and-soldiers effect that resulted in transformation of vesicular aggregates of OPE1 into CD-active helical nanotubes (see schematic picture), as revealed by CD, dynamic light scattering, and atomic force and transmission electron microscopies (TEM). OPE = oligo(p-phenyleneethynylene). (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7729 / 7732

页数：4

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