Gradient copolymers

被引：123

作者：

Beginn, Uwe ^{[1
]}

机构：

[1] Univ Osnabruck, Inst Chem, D-49069 Osnabruck, Germany

来源：

COLLOID AND POLYMER SCIENCE | 2008年 / 286卷 / 13期

关键词：

gradient copolymer; gradient block copolymer; definition; preparation; properties; application;

D O I：

10.1007/s00396-008-1922-y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gradient copolymers represent a relative new class of copolymers containing at least one section of the macromolecule where the chemical composition continuously changes along the polymer chain. Due to their structural relation to block copolymers, microphase-segregated structures can be formed in bulk, in solution, at surfaces, and interfaces exhibiting a blurred, less-defined border region between phases. The article reviews the preparation methods, the main physical peculiarities, and some proposed applications of gradient copolymers.

引用

页码：1465 / 1474

页数：10

共 93 条

[1]

AKOVALI G, 1975, GOV REP ANNOUNCE IND, V75, P52

[2] Single-chain statistics in polymer systems [J].

Aksimentiev, A ;

Holyst, R .

PROGRESS IN POLYMER SCIENCE, 1999, 24 (07) :1045-1093

[3] Phase behavior of gradient copolymers [J].

Aksimentiev, A ;

Holyst, R .

JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (05) :2329-2339

[4] Synthesis and self-association of stimuli-responsive diblock copolymers by living cationic polymerization [J].

Aoshima, S ;

Sugihara, S ;

Shibayama, M ;

Kanaoka, S .

MACROMOLECULAR SYMPOSIA, 2004, 215 :151-163

[5] Synthesis of stimuli-responsive polymers by living polymerization:: Poly(N-isopropylacrylamide) and poly(vinyl ether)s [J].

Aoshima, Sadahito ;

Kanaoka, Shokyoku .

WAX CRYSTAL CONTROL: NANOCOMPOSITES, STIMULI-RESPONSIVE POLYMERS, 2008, 210 (169-208) :169-208

[6]

AREHART SV, 1997, POLYM PREPR AM CHEM, V38, P705

[7]

ASKADSKII AA, 2007, PLASTI MASS, P30

[8] Monomer addition programs to generate constant gradient block copolymers [J].

Beginn, Uwe .

POLYMER, 2006, 47 (19) :6880-6894

[9]

BELLO A, 2000, REV PLAST MODERN, V79, P55

[10] Effect of polymer architecture of amphiphilic poly(2-oxazoline) copolymers on the aggregation and aggregate structure [J].

Bonne, Tune B. ;

Ludtke, Karin ;

Jordan, Rainer ;

Papadakis, Christine M. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2007, 208 (13) :1402-1408

← 1 2 3 4 5 6 7 8 9 10 →