Gradient copolymers

被引:123
作者
Beginn, Uwe [1 ]
机构
[1] Univ Osnabruck, Inst Chem, D-49069 Osnabruck, Germany
关键词
gradient copolymer; gradient block copolymer; definition; preparation; properties; application;
D O I
10.1007/s00396-008-1922-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gradient copolymers represent a relative new class of copolymers containing at least one section of the macromolecule where the chemical composition continuously changes along the polymer chain. Due to their structural relation to block copolymers, microphase-segregated structures can be formed in bulk, in solution, at surfaces, and interfaces exhibiting a blurred, less-defined border region between phases. The article reviews the preparation methods, the main physical peculiarities, and some proposed applications of gradient copolymers.
引用
收藏
页码:1465 / 1474
页数:10
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