Auger decay of the dissociating core-excited states in the HCl and DCl molecules

被引：54

作者：

Kukk, E

Aksela, H

Sairanen, OP

Aksela, S

Kivimaki, A

Nommiste, E

Ausmees, A

Kikas, A

Osborne, SJ

Svensson, S

机构：

[1] UNIV UPPSALA,DEPT PHYS,S-75121 UPPSALA,SWEDEN

[2] ESTONIAN ACAD SCI,INST PHYS,TARTU 2400,ESTONIA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 104卷 / 12期

关键词：

D O I：

10.1063/1.471542

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High-resolution Auger electron spectra from the decay of the Cl 2p-->sigma* excitation in HCl and DCl have been measured. The spectra are analyzed, separating molecular and atomic features, which are assigned to transitions to the HCl (5 sigma 2 pi)(4) sigma* and Cl (3s3p)(6) states, respectively. Auger line shapes, as affected by the molecular dissociation, are studied by comparing the experiment with the results of Monte-Carlo computer simulations based on a semiclassical model. (C) 1996 American Institute of Physics.

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页码：4475 / 4480

页数：6

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