Fabrication and performance test of a catalyst-coated membrane from direct spray deposition

被引:53
作者
Sun, Liangliang [1 ]
Ran, Ran [1 ]
Wang, Guixing [1 ]
Shao, Zongping [1 ]
机构
[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
关键词
catalyst-coated membranes; ethylene glycol; PEMFCs; Nafion;
D O I
10.1016/j.ssi.2008.01.081
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Catalyst-coated membranes (CCMs) play an important role in the PEMFCs. The direct-spraying deposition method that is using ethyleneglycol (EG) soaked Nafion membrane and the catalyst ink with isopropyl alcohol as the primary liquid media and small amount of EG as additive has been developed for fabrication of high-quality CCMs. The properties of the CCMs have been analyzed by SEM, I-V and EIS characterization. Both modification of catalyst layers and membrane surfaces with Nafion had significant impacts on the cell performance. On favorable conditions, a peak power density of similar to 430mW/cm(2) could be achieved for a H-2 vertical bar O-2 cell at ambient pressure and total Pt loading of 0.3mg/cm(2) including both the anode and cathode. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:960 / 965
页数:6
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