18O incorporation in the oxidation of N-methylcarbazole by lignin peroxidase and a model compound:: a mechanistic insight into the oxidative N-demethylation of aromatic tertiary amines

被引：2

作者：

Baciocchi, E

Gerini, MF

Lapi, A

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

[2] Univ Roma La Sapienza, Ctr CNR Studio Meccanismi Reaz, I-00185 Rome, Italy

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 09期

关键词：

D O I：

10.1039/b201492k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using O-18 labelled reactants and/or solvent, the origin of the oxygen in the products of the oxidation of N-methylcarbazole by H2O2 catalysed by lignin peroxidase and a model compound has been determined, so getting important information about the mechanism of the oxidative N-demethylation of aromatic tertiary amines.

引用

页码：946 / 947

页数：2

共 16 条

[11] COMPARISON OF LIGNIN PEROXIDASE, HORSERADISH-PEROXIDASE AND LACCASE IN THE OXIDATION OF METHOXYBENZENES [J].