Asymmetric epoxidation of olefins by chiral dioxiranes generated in situ from ketones of D-(-)-quinic acid

被引：49

作者：

Adam, W ^{[1
]}

Saha-Möller, CR ^{[1
]}

Zhao, CG ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 14期

关键词：

D O I：

10.1016/S0957-4166(99)00250-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The in situ generated dioxiranes (Caroate as peroxide source) of the optically active ketones 4a and 4b, which may be conveniently prepared from D-(-)-quinic acid, serve as effective oxidants for the asymmetric epoxidation (ee values up to ca. 90% with 4a) of prochiral olefins. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2749 / 2755

页数：7

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