Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites

被引:120
作者
Reetz, Manfred T. [1 ]
Li, Xiaoguang [1 ]
机构
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
D O I
10.1039/b602320g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A chiral diphosphonite, derived from BINOL and with an achiral diphenyl ether backbone, is an excellent ligand for the Ir-catalyzed asymmetric hydrogenation of quinolines; achiral P-ligands serving as possible additives (ee = 73-96%).
引用
收藏
页码:2159 / 2160
页数:2
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