Facile Fabrication of TiO2/SrTiO3 Composite Nanofibers by Electrospinning for High Efficient H2 Generation

被引:46
作者
Bai, Hongwei [1 ]
Liu, Zhaoyang [1 ]
Sun, Darren D. [1 ]
机构
[1] Nanyang Technol Univ, Sch Civil & Environm Engn, Singapore 639798, Singapore
关键词
TIO2 NANOTUBE PHOTOCATALYST; HYDROGEN-PRODUCTION; HOLLOW NANOFIBERS; NANOSTRUCTURES; NANOPARTICLES; ARCHITECTURE; NANOWIRES; MEMBRANE; SRTIO3;
D O I
10.1111/jace.12071
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Using electrospinning, specially prepared Ti and Sr precursor TiO2/SrTiO3 composite nanofibers were successfully fabricated. This would ensure the close and uniform contact between TiO2 and SrTiO3, which significantly contributes to the electrons transfer at the interface between the two semiconductors with different band gaps. Meanwhile, the long fibrous structure of TiO2/SrTiO3 composite nanofibers would further ease the electron transfer, enlarge the specific surface area, and enhance the light absorption capability thus leading to the improvement of photocatalytic efficiency. Because of the above-mentioned advantages, the TiO2/SrTiO3 composite nanofibers exhibited higher photocatalytic H2 generation efficiency over bare TiO2 nanofibers in a water/methanol sacrificial reagent system under the irradiation of UV light.
引用
收藏
页码:942 / 949
页数:8
相关论文
共 46 条
[1]   Photoelectrochemical hydrogen production from water/methanol decomposition using Ag/TiO2 nanocomposite thin films [J].
Alenzi, Naser ;
Liao, Wei-Ssu ;
Cremer, Paul S. ;
Sanchez-Torres, Viviana ;
Wood, Thomas K. ;
Ehlig-Economides, Christine ;
Cheng, Zhengdong .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (21) :11768-11775
[2]   Dynamic electrochemical investigations of hydrogen oxidation and production by enzymes and implications for future technology [J].
Armstrong, Fraser A. ;
Belsey, Natalie A. ;
Cracknell, James A. ;
Goldet, Gabrielle ;
Parkin, Alison ;
Reisner, Erwin ;
Vincent, Kylie A. ;
Wait, Annemarie F. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :36-51
[3]   An overview on semiconductor particulate systems for photoproduction of hydrogen [J].
Ashokkumar, M .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1998, 23 (06) :427-438
[4]   Hierarchical SrTiO3/TiO2 nanofibers heterostructures with high efficiency in photocatalytic H2 generation [J].
Bai, Hongwei ;
Juay, Jermyn ;
Liu, Zhaoyang ;
Song, Xiaoxiao ;
Lee, Siew Siang ;
Sun, Darren Delai .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 125 :367-374
[5]   A hierarchically structured and multifunctional membrane for water treatment [J].
Bai, Hongwei ;
Liu, Zhaoyang ;
Sun, Darren Delai .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 111 :571-577
[6]   Hierarchical ZnO/Cu "corn-like" materials with high photodegradation and antibacterial capability under visible light [J].
Bai, Hongwei ;
Liu, Zhaoyang ;
Sun, Darren Delai .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (13) :6205-6210
[7]   Hierarchically multifunctional TiO2 nano-thorn membrane for water purification [J].
Bai, Hongwei ;
Liu, Zhaoyang ;
Sun, Darren Delai .
CHEMICAL COMMUNICATIONS, 2010, 46 (35) :6542-6544
[8]   Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects [J].
Bak, T ;
Nowotny, J ;
Rekas, M ;
Sorrell, CC .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (10) :991-1022
[9]   Nanotechnology for photolytic hydrogen production: Colloidal anodic oxidation [J].
Best, James P. ;
Dunstan, Dave E. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (18) :7562-7578
[10]   A Facile in Situ Hydrothermal Method to SrTiO3/TiO2 Nanofiber Heterostructures with High Photocatalytic Activity [J].
Cao, Tieping ;
Li, Yuejun ;
Wang, Changhua ;
Shao, Changlu ;
Liu, Yichun .
LANGMUIR, 2011, 27 (06) :2946-2952