Biomass to fuels:: A water-free process for biodiesel production with phosphazene catalysts

被引：11

作者：

Cerro-Alarcon, Miriam ^{[1
]}

Corma, Avelino ^{[1
]}

Iborra, Sara ^{[1
]}

Gomez, Juan Pedro ^{[2
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] Ctr Invest Repsol YPF, Madrid 28931, Spain

来源：

APPLIED CATALYSIS A-GENERAL | 2008年 / 346卷 / 1-2期

关键词：

biomass to fuels; biodiesel; transesterification; alcoholysis; organocatalysis; phosphazene catalyst;

D O I：

10.1016/j.apcata.2008.05.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Non-ionic triamino(imino)phosphoranes (phosphazenes) give excellent results as base catalysts for the water-free alcoholysis of vegetable fatty esters. Two phosphazene catalysts, with different intrinsic basicities, P-1-t-Bu and P-4-t-Bu, together with reaction parameters, such as temperature, alcohol/oil molar ratio, or catalyst concentration, have been studied. It was found that activity can be directly correlated to the basicity of the catalyst. Very high biodiesel yields (93-95% mol) were achieved under mild reaction conditions with methanol and ethanol. The catalyst can be recovered and recycled. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：52 / 57

页数：6

共 31 条

[21] Possible methods for biodiesel production [J].

Marchetti, J. M. ;

Miguel, V. U. ;

Errazu, A. F. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2007, 11 (06) :1300-1311

[22] Biodiesel from castor oil: A comparison of ethanolysis versus methanolysis [J].

Meneghetti, Simoni M. Plentz ;

Meneghetti, Mario R. ;

Wolf, Carlos R. ;

Silva, Eid C. ;

Lima, Gilvan E. S. ;

Silva, Laelson de Lira ;

Serra, Tatiana M. ;

Cauduro, Fernanda ;

de Oliveira, Lenise G. .

ENERGY & FUELS, 2006, 20 (05) :2262-2265

[23] Improved conversion of plant oils and animal fats into biodiesel, and co-product [J].

Muniyappa, PR ;

Brammer, SC ;

Noureddini, H .

BIORESOURCE TECHNOLOGY, 1996, 56 (01) :19-24

[24]

PLANK C, 1992, HRC-J HIGH RES CHROM, V15, P609

[25]

Schuchardt U, 1998, J BRAZIL CHEM SOC, V9, P199

[26]

STERN R, 1999, Patent No. 5908946

[27] Hydroprocessed vegetable oils for diesel fuel improvement [J].

Stumborg, M ;

Wong, A ;

Hogan, E .

BIORESOURCE TECHNOLOGY, 1996, 56 (01) :13-18

[28]

TAFT RW, 1947, J AM CHEM SOC, V69, P2058

[29]

Vasudevan P, 2005, J SCI IND RES INDIA, V64, P822

[30] Integrated biodiesel production:: a comparison of different homogeneous catalysts systems [J].

Vicente, G ;

Martínez, M ;

Aracil, J .

BIORESOURCE TECHNOLOGY, 2004, 92 (03) :297-305

← 1 2 3 4 →