a new method for the synthesis of Z-enediones via IBX-mediated oxidative rearrangement of 2-alkynyl alcohol systems

被引：41

作者：

Crone, B ^{[1
]}

Kirsch, SF ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 07期

关键词：

D O I：

10.1039/b515838a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

o-Iodoxybenzoic acid (IBX) was found to mediate the conversion of alpha-alkynyl alcohols into Z-enediones under notably mild conditions via a novel rearrangement mechanism (33-65% yield, 13 examples).

引用

页码：764 / 766

页数：3

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