Synthesis of Hexagonal-Phase Core-Shell NaYF4 Nanocrystals with Tunable Upconversion Fluorescence

被引:352
作者
Qian, Hai-Sheng [1 ]
Zhang, Yong [1 ,2 ]
机构
[1] Natl Univ Singapore, Fac Engn, Div Bioengn, Singapore 117574, Singapore
[2] Natl Univ Singapore, Nanosci & Nanotechnol Inst, Singapore 117576, Singapore
关键词
D O I
10.1021/la802343f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hexagonal-phasecore-shell-structured NaYF4:Yb,Tm@beta-NaYF4:Yb,Er and beta-NaYF4:Yb,Tm@-NaYF4:Yb,Er@#NaYF4:Yb,Tm nanocrystals were synthesized by a seeded growth approach. beta-NaYF4:Yb,Tm nanocrystals with 20 nm diameter were used as seed crystals to induce the growth of beta-NaYF4:Yb,Er and then beta-NaYF4:Yb,Tm crystals, resulting in the formation of core-shell-structured nanocrystals with upconverting lanthanide ions Tm and Er doped in the core and shell, respectively.
引用
收藏
页码:12123 / 12125
页数:3
相关论文
共 43 条
[1]   Structural and spectroscopic characterization of active sites in a family of light-emitting sodium lanthanide tetrafluorides [J].
Aebischer, A ;
Hostettler, M ;
Hauser, J ;
Krämer, K ;
Weber, T ;
Güdel, HU ;
Buergi, HB .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (17) :2802-2806
[2]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[3]  
Banin U, 2007, NAT MATER, V6, P625, DOI 10.1038/nmat1993
[4]   Synthesis of colloidal upconverting NaYF4: Er3+/Yb3+ and Tm3+/Yb3+ monodisperse nanocrystals [J].
Boyer, John-Christopher ;
Cuccia, Louis A. ;
Capobianco, John A. .
NANO LETTERS, 2007, 7 (03) :847-852
[5]   Synthesis of colloidal upconverting NaYF4 nanocrystals doped with Er3+, Yb3+ and Tm3+, Yb3+ via thermal decomposition of lanthanide trifluoroacetate precursors [J].
Boyer, John-Christopher ;
Vetrone, Fiorenzo ;
Cuccia, Louis A. ;
Capobianco, John A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) :7444-7445
[6]   EFFICIENCY OF YB3+-ER3+ ACTIVATED UP-CONVERSION PHOSPHORS [J].
BRIL, A ;
SOMMERDIJK, JL ;
JAGER, AWD .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (05) :660-663
[7]   CRYSTAL STRUCTURE OF HEXAGONAL SODIUM NEODYMIUM FLUORIDE AND RELATED COMPOUNDS [J].
BURNS, JH .
INORGANIC CHEMISTRY, 1965, 4 (06) :881-&
[8]   A three-color, solid-state, three-dimensional display [J].
Downing, E ;
Hesselink, L ;
Ralston, J ;
Macfarlane, R .
SCIENCE, 1996, 273 (5279) :1185-1189
[9]   Shaping binary metal nanocrystals through epitaxial seeded growth [J].
Habas, Susan E. ;
Lee, Hyunjoo ;
Radmilovic, Velimir ;
Somorjai, Gabor A. ;
Yang, Peidong .
NATURE MATERIALS, 2007, 6 (09) :692-697
[10]   Highly efficient multicolour upconversion emission in transparent colloids of lanthanide-doped NaYF4 nanocrystals [J].
Heer, S ;
Kömpe, K ;
Güdel, HU ;
Haase, M .
ADVANCED MATERIALS, 2004, 16 (23-24) :2102-+