Interpenetration control in metal-organic frameworks for functional applications

被引：495

作者：

Jiang, Hai-Long ^{[1
,2
]}

Makal, Trevor A. ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Univ Sci & Technol China, Div Nanomat & Chem, Hefei Natl Lab Phys Sci Microscale, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 15-16期

关键词：

Interpenetration; Metal-organic framework; Coordination polymer; Surface area; Hydrogen uptake; INFINITE POLYMERIC FRAMEWORKS; 2D POLYROTAXANE NETWORK; COORDINATION POLYMERS; HYDROGEN STORAGE; SELECTIVE SORPTION; DIAMONDOID NETWORK; MOLECULAR LADDERS; CATENATION ISOMERISM; STRUCTURAL MOTIFS; CRYSTAL-STRUCTURE;

D O I：

10.1016/j.ccr.2013.03.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interpenetration in metal-organic frameworks (MOFs) is an intriguing phenomenon with significant impacts on the structure, porous nature, and functional applications of MOFs. In this review, we provide an overview of interpenetration involved in MOFs or coordination polymers with different dimensionalities and property changes (especially gas uptake capabilities and catalysis) caused by framework interpenetration. Successful approaches for control of interpenetration in MOFs have also been introduced and summarized. Published by Elsevier B.V.

引用

页码：2232 / 2249

页数：18

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