[(η5-C5H5)Fe(CO)2]2B(2,4,6-Me3C6H2):: synthesis, spectroscopic and structural characterization of a transition metal complex containing an unsupported bridging borylene ligand

被引：42

作者：

Aldridge, S ^{[1
]}

Coombs, DL ^{[1
]}

Jones, C ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 08期

关键词：

D O I：

10.1039/b201415g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterisation of the dinuclear iron complex [(eta(5)-C5H5)Fe(CO)(2)](2)B(2,4,6-Me3C6H2) containing an unsupported bridging borylene ligand are reported.

引用

页码：856 / 857

页数：2

共 34 条

[1] Perfluoroaryl boryl complexes: synthesis, spectroscopic and structural characterisation of a complex containing the bis(pentafluorophenyl)boryl ligand [J].

Aldridge, S ;

Al-Fawaz, A ;

Calder, RJ ;

Dickinson, AA ;

Willock, DJ ;

Light, ME ;

Hursthouse, MB .

CHEMICAL COMMUNICATIONS, 2001, (18) :1846-1847

[2] Linking of metal centres through boryl ligands:: synthesis, spectroscopic and structural characterisation of a symmetrically bridged boryl complex CpFe(CO)2BO2C6H2O2BFe(CO)2Cp [J].

Aldridge, S ;

Calder, RJ ;

Dickinson, AA ;

Willock, DJ ;

Steed, JW .

CHEMICAL COMMUNICATIONS, 2000, (15) :1377-1378

[3] Transition metal complexes of boron - synthesis, structure and reactivity [J].

Braunschweig, H ;

Colling, M .

COORDINATION CHEMISTRY REVIEWS, 2001, 223 :1-51

[4]

Braunschweig H, 1998, ANGEW CHEM INT EDIT, V37, P3179, DOI 10.1002/(SICI)1521-3773(19981204)37:22<3179::AID-ANIE3179>3.0.CO

[5]

2-Z

[6]

Braunschweig H, 2001, ANGEW CHEM INT EDIT, V40, P4198, DOI 10.1002/1521-3773(20011119)40:22<4198::AID-ANIE4198>3.0.CO

[7]

2-E

[8]

Braunschweig H, 2001, ANGEW CHEM INT EDIT, V40, P2298, DOI 10.1002/1521-3773(20010618)40:12<2298::AID-ANIE2298>3.0.CO

[9]

2-E

[10] New borylene complexes of the type [mu-BX{(eta(5)-C5H5Me)Mn(CO)(2)}(2)]: Substitution reactions at the metal-coordinated borylene moiety [J].

Braunschweig, H ;

Muller, M .

CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (09) :1295-1298

← 1 2 3 4 →