A chiral bis-N-oxide isoelectronic with Jacobsen's salen ligand

被引:27
作者
Dyker, G [1 ]
Hölzer, B [1 ]
Henkel, G [1 ]
机构
[1] Univ Duisburg Gesamthsch, Inst Syntheschem, Fachbereich 6, D-47048 Duisburg, Germany
关键词
D O I
10.1016/S0957-4166(99)00347-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A chiral bis-N-oxide as a tetradentate ligand for various transition metals is introduced. A Cu(II)-complex is fully characterized including its X-ray structure and the corresponding Cu(I)-complex proved to be an active catalyst for asymmetric cyclopropanation. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3297 / 3307
页数:11
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