Synthesis of novel enantiomerically pure trianglimine and trianglamine macrocycles

被引：67

作者：

Kuhnert, N ^{[1
]}

Strassnig, C ^{[1
]}

Lopez-Periago, AM ^{[1
]}

机构：

[1] Univ Surrey, Dept Chem, Synth Biol & Organ Chem Lab, Guildford GU2 7HX, Surrey, England

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(02)00065-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a series trianglimine macrocycles is described using a [3+3] cyclocondensation strategy between a 1,2-diamine and an aromatic dicarboxaldehyde. The novel compounds have been prepared in enantiomerically pure form and their ring sizes range from 30 to 42. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：123 / 128

页数：6

共 23 条

[1] CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES [J].

BOHMER, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :713-745

[2]

BURKERT U, 1982, ACS MONOGRAPH, V177

[3] (3+3)-Cyclocondensation of the enantiopure and racemic forms of trans-1,2-diaminocyclohexane with terephthaldehyde.: Formation of diastereomeric molecular triangles and their stereoselective solid-state stacking into microporous chiral columns [J].

Chadim, M ;

Budesínsky, M ;

Hodacová, J ;

Závada, J ;

Junk, PC .

TETRAHEDRON-ASYMMETRY, 2001, 12 (01) :127-133

[4] SOME CYCLIC TETRA-AMINES + THEIR METAL-ION COMPLEXES .I. 2 ISOMERIC HEXAMETHYLTETRA-AZACYCLOTETRADECANES + THEIR COPPER(2) + NICKEL )2) COMPLEXES [J].

CURTIS, NF .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (AUG) :2644-&

[5] TRANSITION-METAL COMPLEXES WITH ALIPHATIC SCHIFF BASES .1. NICKEL(II) COMPLEXES WITH N-ISOPROPYLIDENE-ETHYLENEDIAMINE SCHIFF BASES [J].

CURTIS, NF .

JOURNAL OF THE CHEMICAL SOCIETY, 1960, (NOV) :4409-4413

[6]

de Namor AFD, 1998, CHEM REV, V98, P2495

[7] Designing large triangular chiral macrocycles: Efficient [3+3] diamine-dialdehyde condensations based on conformational bias [J].

Gawronski, J ;

Kolbon, H ;

Kwit, M ;

Katrusiak, A .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (18) :5768-5773

[8]

Gutsche C.D., 1998, CALIXARENES REVISITE

[9]

Gutsche C. D., 1989, CALIXARENES MONOGRAP

[10] CALIXARENES .27. SYNTHESIS, CHARACTERIZATION, AND COMPLEXATION STUDIES OF DOUBLE-CAVITY CALIX[4]ARENES [J].

GUTSCHE, CD ;

SEE, KA .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (16) :4527-4539

← 1 2 3 →