Polymerization of 4-nitrophenyl acrylate under microwave heating conditions

被引：13

作者：

Dikusar, MA

Kubrakova, IV

Chinarev, AA

Bovin, NV

机构：

[1] Russian Acad Sci, Shemyakin Ovchinnikov Inst Bioorgan Chem, Moscow 117997, Russia

[2] VI Vernadskii Inst Geochem & Analyt Chem, Moscow 117975, Russia

来源：

RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY | 2001年 / 27卷 / 06期

关键词：

microwave heating; multivalent glycoconjugates; poly(4-nitrophenyl actylate); radical polymerization;

D O I：

10.1023/A:1012949005183

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The 2,2'-azodiisobutyronitrile-induced radical polymerization in solution of 4-nitrophenyl acrylate was performed under microwave heating at a frequency of 2.45 GHz. This approach allows the control of the molecular weight of poly(4-nitrophenyl acrylate) used in the synthesis of multivalent glycoconjugates. It was found that the polymerization of 4-nitrophenyl acrylate under microwave irradiation results in products with a narrower molecular mass distribution than at conventional heating.

引用

页码：408 / 412

页数：5

共 20 条

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