Using resonance energy transfer to improve exciton harvesting in organic-inorganic hybrid photovoltaic cells

被引:145
作者
Liu, YX
Summers, MA
Edder, C
Fréchet, JMJ
McGehee, MD [1 ]
机构
[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
[2] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
[3] Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA
关键词
D O I
10.1002/adma.200501307
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The effective exciton diffusion length of poly(3-hexylthiophene) (P3HT) can be improved with resonance-energy transfer from P3HT to poly(N-dodecyl-2,5-bis(2'-thienyl)pyrrole-2,1,3-benzothia-diazole) (PTPTB), a low-bandgap polymer, which results in a threefold increase of the photocurrent. Directional resonance energy transfer to the exciton-splitting interface has the potential to overcome a number of limitations associated with exciton transport in polymer photovoltaic cells.
引用
收藏
页码:2960 / +
页数:6
相关论文
共 34 条
[1]  
Arango AC, 2000, ADV MATER, V12, P1689, DOI 10.1002/1521-4095(200011)12:22<1689::AID-ADMA1689>3.0.CO
[2]  
2-9
[3]   Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].
Bach, U ;
Lupo, D ;
Comte, P ;
Moser, JE ;
Weissörtel, F ;
Salbeck, J ;
Spreitzer, H ;
Grätzel, M .
NATURE, 1998, 395 (6702) :583-585
[4]   Spontaneous emission and energy transfer in the optical microcavity [J].
Barnes, WL .
CONTEMPORARY PHYSICS, 2000, 41 (05) :287-300
[5]  
Barnes WL, 1998, J MOD OPTIC, V45, P661, DOI 10.1080/09500349808230614
[6]   Efficient hybrid solar cells from zinc oxide nanoparticles and a conjugated polymer [J].
Beek, WJE ;
Wienk, MM ;
Janssen, RAJ .
ADVANCED MATERIALS, 2004, 16 (12) :1009-+
[7]  
Brabec CJ, 2002, ADV FUNCT MATER, V12, P709, DOI 10.1002/1616-3028(20021016)12:10<709::AID-ADFM709>3.0.CO
[8]  
2-N
[9]   Charge transport in TiO2/MEH-PPV polymer photovoltaics -: art. no. 125205 [J].
Breeze, AJ ;
Schlesinger, Z ;
Carter, SA ;
Brock, PJ .
PHYSICAL REVIEW B, 2001, 64 (12)
[10]   Conjugated polymer photovoltaic cells [J].
Coakley, KM ;
McGehee, MD .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4533-4542