Synthesis of new chiral thiazoline-containing ligands

被引:58
作者
Abrunhosa, I [1 ]
Gulea, M [1 ]
Levillain, J [1 ]
Masson, S [1 ]
机构
[1] Univ Caen, ISMRA, UMR CNRS 6507, Lab Chim Mol & Thioorgan, F-14050 Caen, France
关键词
D O I
10.1016/S0957-4166(01)00481-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New chiral ligands. including bi- and tridentate thiazoline derivatives, analogues of known oxazolines, have been synthesized by it general and convenient procedure. starting from dithioesters and commercial enantiopure 2-aminoalcohols. A preliminary Lest shows the ability of such ligands to act as asymmetric catalysts in Pd-catalyzed allylic substitution reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码:2851 / 2859
页数:9
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