Limiting Internal Short-Circuit Damage by Electrode Partition for Impact-Tolerant Li-Ion Batteries

被引:74
作者
Naguib, Michael [1 ,4 ]
Allu, Srikanth [2 ]
Simunovic, Srdjan [2 ]
Li, Jianlin [3 ]
Wang, Hsin [1 ]
Dudney, Nancy J. [1 ]
机构
[1] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
[2] Oak Ridge Natl Lab, Comp Sci & Math Div, Oak Ridge, TN 37831 USA
[3] Oak Ridge Natl Lab, Energy & Transportat Sci Div, Oak Ridge, TN 37831 USA
[4] Tulane Univ, Dept Phys & Engn Phys, New Orleans, LA 70118 USA
关键词
FRACTURE-TOUGHNESS; METALLIC FOILS; LITHIUM; SIMULATION; STRAIN; CELL;
D O I
10.1016/j.joule.2017.11.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
We report on a unique safety mechanism introduced to the Li-ion battery design to mitigate the effects of a mechanical impact event by limiting the current moving through resulting internal shorts, thereby preventing thermal runaway. "Slitted'' electrodes and current collectors would electrically isolate the impacted parts of the electrodes before puncturing the separator. Batteries with such "slitted'' electrodes were shown to perform normally prior to the mechanical impact. A proof-of-concept experiment showed that the battery with modified electrodes survived significant mechanical deformation without any change in the open-circuit voltage of the battery. It is interesting to note that, after the impact event, the modified battery was still viable with a reversible capacity of about 93% of that before the indentation test, while the standard battery was no longer functional.
引用
收藏
页码:155 / 167
页数:13
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