Chemical analysis of a polysaccharide of unripe (green) tomato (Lycopersicon esculentum)

被引:32
作者
Chandra, Krishnendu [1 ]
Ghosh, Kaushik [1 ]
Ojha, Arnab K. [1 ]
Islam, Syed S. [1 ]
机构
[1] Vidyasagar Univ, Dept Chem & Chem Technol, Midnapore 721102, W Bengal, India
关键词
Green tomato; Lycopersicon esculentum; Polysaccharide; Structure; NMR spectroscopy; PLEUROTUS-SAJOR-CAJU; EDIBLE MUSHROOM; ASTRAEUS-HYGROMETRICUS; STRUCTURAL-ANALYSIS; AQUEOUS EXTRACT; IN-VITRO; FRUIT; OLIGOSACCHARIDES; CONFIGURATION; HETEROGLYCAN;
D O I
10.1016/j.carres.2009.08.029
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
070307 [化学生物学]; 071010 [生物化学与分子生物学];
摘要
A polysaccharide (PS-I) isolated from the aqueous extract of the unripe (green) tomatoes (Lycopersicon esculentum) consists Of D-galactose, D-methyl galacturonate, D-arabinose, L-arabinose, and L-rhamnose. Structural investigation of the polysaccharide was carried out using total acid hydrolysis, methylation analysis, periodate oxidation study, and NMR studies (H-1, C-13, DQF-COSY, TOCSY, NOESY, ROESY, HMQC, and HMBC). On the basis of above-mentioned experiments the structure of the repeating unit of the polysaccharide (PS-I) was established as: [GRAPHICS] (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2188 / 2194
页数:7
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