First successful enantiomeric discrimination of chiral alkanes using NMR spectroscopy

被引:54
作者
Sarfati, M [1 ]
Courtieu, J [1 ]
Lesot, P [1 ]
机构
[1] Univ Paris 11, Inst Chim Mol Orsay, Chim Organ Struct Lab, CNRS,ESA 8074, F-91405 Orsay, France
关键词
D O I
10.1039/b002806l
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Natural abundance deuterium NMR spectroscopy in a chiral polypeptide liquid crystal solvent (PBLG) is used to successfully discriminate between chiral alkanes.
引用
收藏
页码:1113 / 1114
页数:2
相关论文
共 9 条
[1]   Deuterium NMR stereochemical analysis of threo-erythro isomers bearing remote stereogenic centres in racemic and non-racemic liquid crystalline solvents [J].
Canlet, C ;
Merlet, D ;
Lesot, P ;
Meddour, A ;
Loewenstein, A ;
Courtieu, J .
TETRAHEDRON-ASYMMETRY, 2000, 11 (09) :1911-1918
[2]   POLYPEPTIDE LIQUID-CRYSTALS - A DEUTERIUM NMR-STUDY [J].
CZARNIECKA, K ;
SAMULSKI, ET .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1981, 63 (1-4) :205-214
[3]  
KONIG WA, 1990, HRC-J HIGH RES CHROM, V13, P702
[4]   Calculation of the molecular ordering parameters of (+/-)-3-butyn-2-ol dissolved in an organic solution of poly(gamma-benzyl-L-glutamate) [J].
Lesot, P ;
Merlet, D ;
Courtieu, J ;
Emsley, JW ;
Rantala, TT ;
Jokisaari, J .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (31) :5719-5724
[5]   VISUALIZATION OF ENANTIOMERS IN A POLYPEPTIDE LIQUID-CRYSTAL SOLVENT THROUGH C-13 NMR-SPECTROSCOPY [J].
LESOT, P ;
MERLET, D ;
MEDDOUR, A ;
COURTIEU, J ;
LOEWENSTEIN, A .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (09) :1371-1375
[6]   Enantiomeric visualization using proton-decoupled natural abundance deuterium NMR in poly(γ-benzyl-L-glutamate) liquid crystalline solutions [J].
Lesot, P ;
Merlet, D ;
Loewenstein, A ;
Courtieu, J .
TETRAHEDRON-ASYMMETRY, 1998, 9 (11) :1871-1881
[7]  
Lindon JC., 1975, NMR SPECTROSCOPY USI
[8]   Two-dimensional deuterium NMR spectroscopy of chiral molecules oriented in a polypeptide liquid crystal: Applications for the enantiomeric analysis through natural abundance deuterium NMR [J].
Merlet, D ;
Ancian, B ;
Courtieu, J ;
Lesot, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (22) :5249-5258
[9]   NMR DETERMINATION OF ENANTIOMERIC PURITY [J].
PARKER, D .
CHEMICAL REVIEWS, 1991, 91 (07) :1441-1457