Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs)

被引：33

作者：

Akzinnay, Said ^{[1
]}

Bisaro, Fabrice ^{[2
]}

Cazin, Catherine S. J. ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 38期

关键词：

N-HETEROCYCLIC CARBENE; SUZUKI-MIYAURA; ARYL CHLORIDES; COMPLEX; NHC;

D O I：

10.1039/b910415a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrodehalogenation of polychlorinated phenyls and biphenyls (PCBs), catalysed by palladium N-heterocyclic carbene complexes, proceeds with excellent yields, at very low catalyst loadings and at room temperature, using isopropanol as the hydrogen source and NaOH as the base.

引用

页码：5752 / 5753

页数：2

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