Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(μ-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene)

被引：118

作者：

Diebolt, Olivier ^{[1
]}

Braunstein, Pierre ^{[2
]}

Nolan, Steven P. ^{[1
]}

Cazin, Catherine S. J. ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Univ Strasbourg 1, Chim Coordinat Lab, CNRS, Inst Chim,UMR 7177, F-67070 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 27期

关键词：

D O I：

10.1039/b804695f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A straightforwardly synthesised complex, [Pd(mu-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.

引用

页码：3190 / 3192

页数：3

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