UCST wetting transitions of polyzwitterionic brushes driven by self-association

被引：227

作者：

Azzaroni, O ^{[1
]}

Brown, AA ^{[1
]}

Huck, WTS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 1EW, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 11期

关键词：

ion pairs; polymers; surface chemistry; thin films; zwitterions;

D O I：

10.1002/anie.200503264

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A sweeping success: The surface-initiated, atom-transfer radical polymerization of [2-(methacryloyloxy)ethyl]dimethyl(3-sulfopropyl) ammonium hydroxide (MEDSAH) on silicon and gold surfaces leads to homogeneous and patterned brushes of poly-MEDSAH. The association state of the zwitterionic side-groups is determined (see picture; wettability of thin (left) and thick (right) brushes). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1770 / 1774

页数：5

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