Structures of [Co(II)(L)(NO3)(HOCH3)n]BPh4 (n=4, 5) complexes (L = cis,cis-1,3,5-triaminocyclohexane-based ligand):: structural 'snapshots' of anion binding to a metal centre

被引：25

作者：

Boxwell, CJ ^{[1
]}

Walton, PH ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904802b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of [Co(II)(L)(NO3)(HOCH3)(n)]BPh4 {L = cis,cis-1,3,5-tri[(4-tert- butylphenyl)propenylideneamino]cyclohexane} complexes demonstrate the role of solvent molecules in the stabilisation of anions within a solvated cavity: the structures can be compared with bicarbonate binding in the active site of carbonic anhydrase.

引用

页码：1647 / 1648

页数：2

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