Conjugation of Selenophene with Bipyridine for a High Molar Extinction Coefficient Sensitizer in Dye-Sensitized Solar Cells

被引：67

作者：

Gao, Feifei ^{[1
]}

Cheng, Yueming ^{[1
]}

Yu, Qingjiang ^{[1
]}

Liu, Shi ^{[1
,2
]}

Shi, Dong ^{[1
]}

Li, Yunhui ^{[2
]}

Wang, Peng ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Changchun Univ Sci & Technol, Sch Chem & Environm Engn, Changchun 130022, Peoples R China

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 06期

基金：

美国国家科学基金会;

关键词：

NANOCRYSTALLINE TITANIUM-DIOXIDE; CONVERSION-EFFICIENCY; ENERGY-CONVERSION; CHARGE-TRANSFER; TIO2; ENHANCE; PERFORMANCE; COMPLEXES;

D O I：

10.1021/ic802289e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A high molar extinction coefficient heteroleptic polypyridyl ruthenium sensitizer, featuring a conjugated electron-rich selenophene unit in its ancillary ligand, has been synthesized and demonstrated as an efficient sensitizer in dye-sensitized solar cells. A nanocrystalline titania film stained with this sensitizer shows improved optical absorptivity, which is highly desirable for dye-sensitized solar cells with a thin photoactive layer. With preliminary testing, this sensitizer has already achieved a high efficiency of 10.6% measured under the air mass 1.5 global conditions.

引用

页码：2664 / 2669

页数：6

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