Schiff-base complexes of metal(II) as new catalysts in the high-regioselective conversion of epoxides to halo alcohols by means of elemental halogen

被引：61

作者：

Sharghi, H ^{[1
]}

Naeimi, H ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1999年 / 72卷 / 07期

关键词：

D O I：

10.1246/bcsj.72.1525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ring opening of epoxides with elemental iodine and bromine in the presence of some Schiff-base complexes of the first-row transition metal(II) as new catalysts affords vicinal iodo alcohols and bromo alcohols in high yields. This new procedure occurs regioselectively under mild conditions in various aprotic solvents. The catalysts are easily recovered and can be reused several times.

引用

页码：1525 / 1531

页数：7

共 48 条

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