Cobalt(II) monoxide nanoparticles embedded in porous carbon nanofibers as a highly reversible conversion reaction anode for Li-ion batteries

被引:65
作者
Ryu, Won-Hee [1 ]
Shin, Jungwoo [1 ]
Jung, Ji-Won [1 ]
Kim, Il-Doo [1 ,2 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, KAIST Inst NanoCentury, Taejon 305701, South Korea
基金
新加坡国家研究基金会;
关键词
RECHARGEABLE LITHIUM BATTERIES; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS; HIGH-CAPACITY; NEGATIVE-ELECTRODE; CHALLENGES; COMPOSITES; CO3O4(110); NANOWIRES; HYBRID;
D O I
10.1039/c3ta01443f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CoO nanoparticles embedded in porous carbon nanofibers (CNFs), which are used as a novel conversion reaction anode electrode, are successfully synthesized via one-step electrospinning and subsequent calcination in an Ar atmosphere. High capacity, excellent cyclability, and superior rate capability are achieved by a highly reversible conversion reaction of CoO nanoparticles and facile electron transport through highly conductive CNFs.
引用
收藏
页码:3239 / 3243
页数:5
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